| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1335645 | Polyhedron | 2006 | 9 Pages |
Abstract
The kinetics of oxidation of mercury(I) with quinoliniumdichromate (QDC) in the presence of micro amounts of palladium(II) catalyst in aqueous sulfuric acid medium has been studied. The active species of oxidant, reductant and catalyst in the reaction medium were understood to be HCrO4-, [Hg2(SO4)HSO4]â and PdCl+, respectively. The autocatalysis by one of the products, chromium(III), was observed.
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Authors
S.A. Chimatadar, T. Basavaraj, S.T. Nandibewoor,