| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1336070 | Polyhedron | 2011 | 5 Pages |
Abstract
⺠Isoelectronic aziridine ligands:azC2H2R2X (3: R = H, X = OH; 4: R = Me, X = NH2). ⺠Neutral and ionic Cu4O4 cubanes:Cu4Br4(3-H)4 (5) and [Cu4(OH)4(4)4]Br4 (7). ⺠Ligand 3-H acts as bridging (η1-N, μ3-O), ligand 4 as chelating ligand (η2-N,Nâ²). ⺠5 is formed from CuBr2 by HBr elimination, 7 from CuBr by redox reaction with O2/H2O. ⺠Complexes 5 and 7 are the first Cu4O4 cubanes with aziridine ligands.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sophie Putzien, Stefan Wirth, J. Nicolas Roedel, Ingo-Peter Lorenz,