| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1336279 | Polyhedron | 2011 | 8 Pages |
Abstract
⺠The crystal and electronic structures of four ruthenium(II) hydrido-carbonyl complexes have been determined. ⺠The electronic spectra of the complexes were calculated with use of the TD-DFT method and associated with the structure of the molecular orbitals of the complexes. ⺠The emission properties of the complexes have been examined. The thiocyanate derivative of the complex with the 2,2â²-dipyridylamine ligand exhibits very intense luminescence compared with the chloride analog. The emission intensification was associated with matching the energy of the d ruthenium orbitals and the Ï-orbitals of NCS-.
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Authors
J.G. MaÅecki, A. MaroÅ,