Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1336280 | Polyhedron | 2011 | 5 Pages |
Abstract
⺠The iron(II) clathrochelate undergoes a radical addition-elimination reactions. ⺠The reaction radical 1,4-dioxane derivatives yield C-alkylated macrobicycles. ⺠Radical substitution as a novel approach to functionalization of the clathrochelates. ⺠The free-radical addition-elimination reaction results in substitution. ⺠The reaction is first example of alkylation of a coordinated ligand with cyclic ether.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mikhail A. Vershinin, Aleksei B. Burdukov, Ilia V. Eltsov, Vladimir A. Reznikov, Evgenii G. Boguslavsky, Yan Z. Voloshin,