| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1336285 | Polyhedron | 2011 | 5 Pages |
Complexes of cadmium(II)–selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, 113Cd, 77Se, 15N and 13C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)2-en] reveals two non-equivalent metal ion centers, both with a distorted octahedral geometry. The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal–organic framework.
Graphical abstractComplexes of cadmium(II)–selenocyanate with several alkyldiamine ligands have been synthesized and characterized by IR, 113Cd, 77Se, 15N and 13C NMR spectroscopy. The X-ray structure of the complex [Cd(SeCN)2-en] reveals two nonequivalent metal ion centers both with a distorted octahedral geometry with 2D metal–organic framework.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Several alkyldiamine selenocyanato cadmium(II) complexes have been synthesized and characterized. ► The X-ray structure of the [Cd(SeCN)2-en] complex reveals two metal ion centers both with a distorted octahedral geometry. ► The combined bridging modes of selenocyanate and ethylenediamine with the blocking mode of a chelating ethylenediamine generate a 2D metal–organic framework.
