| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1336414 | Polyhedron | 2014 | 7 Pages |
A series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu3(μ-dppm)3(μ3-η1-CC-Np)2]BF4 (1), [Cu3(μ-dppm)3(μ3-η1-CCC6H4CN-4)2]BF4 (2) and [{AuP(Tol-p)3(CC)}2Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemistry of the complexes has also been studied in detail by cyclic voltammetry.
Graphical abstractA series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu3(μ-dppm)3(μ3-η1-CC-Np)2]BF4 (1), [Cu3(μ-dppm)3(μ3-η1-CCC6H4CN-4)2]BF4 (2) and [{AuP(Tol-p)3(CC)}2Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemical properties of the complexes have also been studied.Figure optionsDownload full-size imageDownload as PowerPoint slide
