| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1336522 | Polyhedron | 2014 | 10 Pages |
Abstract
Heterometallic VIV-MnII compounds having a 1D polymeric structure {[Mn(VO)(Me2mal)2(H2O)5]·H2O}n and {[Mn(VO)(Bumal)2(H2O)5]·H2O}n were synthesized and characterized. The voltammograms of these complexes in water solution and in paste electrode are similar and appear to be a superposition of two one-electron oxidation steps corresponding to V4+/V5+ and Mn2+/Mn3+ redox transitions.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Polymeric heterometallic dicarboxylates [MIIx(VIVO)xL2x(H2O)y] (MIIÂ =Â Ba, Mn; LÂ =Â Me2mal, Bumal) and their electrochemical study on solid and composite paste electrodes](/preview/png/1336522.png "First Page Preview: Polymeric heterometallic dicarboxylates [MIIx(VIVO)xL2x(H2O)y] (MIIÂ =Â Ba, Mn; LÂ =Â Me2mal, Bumal) and their electrochemical study on solid and composite paste electrodes")
Authors
Evgeniya S. Bazhina, Grigory G. Aleksandrov, Artem S. Bogomyakov, Mikhail A. Kiskin, Salekh M. Masoud, Oleg M. Nikitin, Tatiana V. Magdesieva, Alexey A. Sidorov, Igor L. Eremenko,