Article ID Journal Published Year Pages File Type
1336528 Polyhedron 2014 7 Pages PDF
Abstract
Substituted imidazoles afford pentaborate(1−) salts when reacted with B(OH)3 in MeOH/H2O. This behaviour contrasts with that of imidazole which yields a nonaborate(3−) salt. [1,2,3-Me3C3N2H2][B5O6(OH)4] has its boroxole rings significantly distorted from planar and anionic H-bonded lattice with a unique αααα acceptor site configuration.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Synthesis and X-ray structural studies of pentaborate(1−) salts containing substituted imidazolium cations
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