Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1336621 | Polyhedron | 2014 | 6 Pages |
Abstract
The first example of dodecanuclear chalcohalide rhenium cluster complex, (Et4N)4(Me2NH2)2[Re12CS17Br6] (1), has been synthesized by reaction of polymeric Re12CS17 with excess of Et4NBr in boiling DMF. The compound was fully characterized by set of methods including IR and UV-Vis spectroscopy, elemental analysis, EDS, mass-spectrometry and single-crystal X-ray diffraction analysis. The electronic structure of [Re12CS17Br6]6â was also elucidated by DFT calculations.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yakov M. Gayfulin, Anton I. Smolentsev, Svetlana G. Kozlova, Vadim V. Yanshole, Yuri V. Mironov,