Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1336981 | Polyhedron | 2013 | 7 Pages |
The reaction of Ca(NO3)2·3H2O and Sr(NO3)2 with trimesoyl-tris-glycine (H3L) leads to a two dimensional (2D) [Ca2(HL)2(μ-H2O)(H2O)5]·3H2O (1) and a three dimensional (3D) [Sr2(HL)2(H2O)7]·H2O (2) coordination polymer, respectively, illustrating the substantial influence of the ionic radii of the alkaline earth metals in determining the motif of the final product.
Graphical abstractThe reaction of Ca(NO3)2·3H2O and Sr(NO3)2 with trimesoyl-tris-glycine (H3L) leads to a two dimensional (2D) [Ca2(HL)2(μ-H2O)(H2O)5]·3H2O (1) and a three dimensional (3D) [Sr2(HL)2(H2O)7]·H2O (2) coordination polymer, respectively, illustrating the substantial influence of the ionic radii of the metal centers in determining the motif of the final product.Figure optionsDownload full-size imageDownload as PowerPoint slide