Article ID Journal Published Year Pages File Type
1336981 Polyhedron 2013 7 Pages PDF
Abstract

The reaction of Ca(NO3)2·3H2O and Sr(NO3)2 with trimesoyl-tris-glycine (H3L) leads to a two dimensional (2D) [Ca2(HL)2(μ-H2O)(H2O)5]·3H2O (1) and a three dimensional (3D) [Sr2(HL)2(H2O)7]·H2O (2) coordination polymer, respectively, illustrating the substantial influence of the ionic radii of the alkaline earth metals in determining the motif of the final product.

Graphical abstractThe reaction of Ca(NO3)2·3H2O and Sr(NO3)2 with trimesoyl-tris-glycine (H3L) leads to a two dimensional (2D) [Ca2(HL)2(μ-H2O)(H2O)5]·3H2O (1) and a three dimensional (3D) [Sr2(HL)2(H2O)7]·H2O (2) coordination polymer, respectively, illustrating the substantial influence of the ionic radii of the metal centers in determining the motif of the final product.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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