Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1337269 | Polyhedron | 2009 | 7 Pages |
Abstract
The solid-state thermolysis (420–450 °С) of the new heterometallic coordination polymer [Li2Co2(Piv)6(μ-L)2]n (1, Piv is the anion of pivalic acid, L is 2-amino-5-methylpyridine) followed by annealing of the decomposition products at 500 °С was shown to afford LiCoO2 in quantitative yield. Compound 1 was characterized by X-ray diffraction and magnetic measurements.
Graphical abstractThe solid-state thermolysis (420–450 °С) of the new heterometallic coordination polymer [Li2Co2(Piv)6(μ-L)2]n followed by annealing of the decomposition products at 500 °С was shown to afford LiCoO2 in quantitative yield.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mikhail Bykov, Anna Emelina, Mikhail Kiskin, Aleksei Sidorov, Grigory Aleksandrov, Artem Bogomyakov, Zhanna Dobrokhotova, Vladimir Novotortsev, Igor Eremenko,