Article ID Journal Published Year Pages File Type
1337633 Polyhedron 2009 5 Pages PDF
Abstract
The rhenium(I) complexes [Re(O2CCF3)(CO)3(L)] (1) and [Re(O2CCF3)(CO)2LL′] (L = Ph2POCH2CH2OPPh2; L′ = PPhn(OR)3−n; R = Me, Et; n = 0-2) (2a-f) have been synthesised by the reaction of the parent bromo derivatives with AgO2CCF3. The metal is in a distorted octahedral environment with the trifluoroacetate ligand acting in a monodentate manner.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites
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