Article ID Journal Published Year Pages File Type
1337738 Polyhedron 2008 8 Pages PDF
Abstract
The OsO4-catalysed oxidation of RHPO2- by alkaline Fe(CN)63- is zero order in Fe(CN)63-, first order in OsO4 and Michaelis-Menten kinetics is observed with respect to RHPO2-. Consistent with this the suggested mechanism is:
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Kinetics and mechanism of the Os(VIII)-catalysed oxidation of hypophosphite and phenylphosphinite ion by alkaline hexacyanoferrate(III) ion
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