Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1338298 | Polyhedron | 2007 | 8 Pages |
Abstract
The reaction of [RuHCl(CO)(PPh3)3] with 8-hydroxyquinoline has been examined and a novel ruthenium(II) complex - [RuCl(CO)(PPh3)2(C9H6NO)] - has been obtained. This compound has been studied by IR, UV-Vis (absorption and emission), 1H and 31P NMR spectroscopy, and X-ray crystallography. The molecular orbital diagram of the complex has been calculated with the density functional theory (DFT) method. The spin-allowed singlet-singlet electronic transitions of the complex have been calculated with the time-dependent DFT method, and the UV-Vis spectrum of the compound has been discussed on this basis.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
J.G. MaÅecki, R. Kruszynski, Z. Mazurak,