| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1338339 | Polyhedron | 2007 | 6 Pages |
The synthesis of unsymmetrically substituted phthalocyanines bearing two p-tolyl-sulfonyl (tosyl)amido and six alkylthio moieties was achieved by cyclotetramerisation of two different phthalonitrile derivatives, namely 1,2-di(alkylthio)-4,5-dicyanobenzene and 4,5-dicyano-N,N′-ditosyl-o-phenylenediamine in the presence of an anhydrous metal salt and strong base. The new compounds were characterized by elemental analyses, UV/Vis, IR, NMR and mass spectra. The mesogenic properties of these new materials were studied by differential scanning calorimetry (DSC) and polarizing optical microscopy. The mesogenic properties of these compounds were compared to that of their symmetric analogous, octaalkythia substituted phthalocyanine derivatives.
Graphical abstractThe synthesis and characterization of unsymmetrically substituted phthalocyanines bearing two p-tolyl-sulfonyl (tosyl)amido and six alkylthio moieties were studied. The mesogenic properties of these new materials were described.Figure optionsDownload full-size imageDownload as PowerPoint slide
