Article ID Journal Published Year Pages File Type
1338453 Polyhedron 2007 6 Pages PDF
Abstract
The synthesis of the D(C6H4S)2SbS2CN(CH2R)2 (D = O, R = Me, 1; D = S, R = Me, 2; R = Ph, 3) complexes containing two different types of dithioligands is described. The antimony acceptor atom in complexes 1-3 expands its coordination number from three to five and displays a skew trapezoidal local geometry via an intramolecular transannular D → Sb interaction.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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