Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1338659 | Polyhedron | 2010 | 8 Pages |
Reaction of ReBr(CO)5 with Li[Ph2P(O)NP(O)Ph2] afforded the cryptate Li[Re2(CO)6{μ-Ph2P(O)NP(O)Ph2-κ2O,O’}3]; whereas K[Ph2P(O)NP(O)Ph2] reacted with ReBr(CO)5 to give K[Re2(CO)6{μ-Ph2P(O)NP(O)Ph2-κ2O,O′}{Ph2P(O)NP(O)Ph2-κ2O,O′}2]. Other chalcogen ligands’ salts M[Ph2P(E)NP(E)Ph2], E = Se and S, M = K and Li gave dirhenium carbonyls with bromido and Ph2P(E)NP(E)Ph2, E = Se or S bridges upon reaction with ReBr(CO)5.
Graphical abstractReaction of ReBr(CO)5 with Li[Ph2P(O)NP(O)Ph2] afforded the cryptate Li[Re2(CO)6{μ-Ph2P(O)NP(O)Ph2-κ2O,O′}3]; whereas K[Ph2P(O)NP(O)Ph2] reacted with ReBr(CO)5 to give K[Re2(CO)6{μ-Ph2P(O)NP(O)Ph2-κ2O,O′}{Ph2P(O)NP(O)Ph2-κ2O,O′}2]. Other chalcogen ligands’ salts M[Ph2P(E)NP(E)Ph2], E = Se and S, M = K and Li gave dirhenium carbonyls with bromido and Ph2P(E)NP(E)Ph2, E = Se or S bridges upon reaction with ReBr(CO)5.Figure optionsDownload full-size imageDownload as PowerPoint slide