| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1338735 | Polyhedron | 2007 | 9 Pages |
Abstract
Variations in the magnitude of the 1JSeP coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established.
Graphical abstractThe electronic influence of perfluoroalkyl groups in a range of trisarylphosphines is conveniently assessed using the 1JSeP coupling constant of the trisarylphosphorus(V) selenides.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dave J. Adams, James A. Bennett, Daniel Duncan, Eric G. Hope, Jonathan Hopewell, Alison M. Stuart, Andrew J. West,