| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1338747 | Polyhedron | 2010 | 7 Pages |
Abstract
A variety of phosphorodiamidate compounds were synthesized from the corresponding phosphorodichloridate intermediates and phosphorus oxychloride. These were completely characterized using different spectroscopic methods and single crystal X-ray diffraction studies on one of them. Studies revealed that water in the presence of a mild Lewis acid like ZnCl2 was found to assist the hydrolysis of the P–N linkage. The proof of this concept was effectively realized through the hydrolysis of hexamethylphosphoramide.
Graphical abstractHydrolysis of the P–N bond using a mild Lewis acid like ZnCl2 for new phosphorodiamidate compounds and hexamethylphosphoramide is described.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Payal Malik, Debashis Chakraborty, Venkatachalam Ramkumar,