Article ID Journal Published Year Pages File Type
1338875 Polyhedron 2007 11 Pages PDF
Abstract
The [Co(pentaamine)X]n+ complexes studied bear at least one N-coordinated -CH2-pyridine group. The mechanism for base catalysed hydrolysis can be switched from the classic SN1CB to the pseudo-aminate mechanism, which involves rate limiting deprotonation, by simply changing the leaving group.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Base catalysed substitution reactions of octahedral cobalt(III) complexes: Mechanism switching by changing the leaving group
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