Article ID Journal Published Year Pages File Type
1338886 Polyhedron 2009 6 Pages PDF
Abstract

Commercially available molybdenum(VI) compounds, including molybdenum trioxide, were successfully employed as catalyst precursors in the epoxidation of olefins with urea–hydrogen peroxide adduct (UHP) in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate, [C4mim][PF6]. After oxidation, the corresponding epoxides were isolated by extraction with diethyl ether. Additionally the ionic liquid–catalyst mixture was recycled and reused in further catalytic cycles. The catalytic species is assumed to be an oxodiperoxomolybdenum species which forms in situ. A representative complex of this type was thus isolated and characterised. Reaction of excess 4-methylpyridine-1-oxide (4-MepyO) with MoO3 dissolved in aqueous hydrogen peroxide afforded [Mo(O)(O2)2(4-MepyO)2]·H2O (1) as yellow crystals. Compound 1, an active epoxidation catalyst, was subsequently characterised and its structure determined by X-ray crystallography.

Graphical abstractThe catalytic epoxidation of several olefins, using commercially available molybdenum trioxide as the catalyst precursor and urea–hydrogen peroxide adduct (UHP) as oxidant in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate, [C4mim][PF6], was conducted successfully. After extraction of the products, the ionic liquid–catalyst mixture can be reused in further catalytic cycles.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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