Article ID Journal Published Year Pages File Type
1338899 Polyhedron 2009 5 Pages PDF
Abstract

The synthesis of a novel class of mercury(II) complexes with sugar-derived bidentade isothioureido ligands, by treatment of N-acylated thioureas with an excess of yellow mercury(II) oxide in aqueous acetonitrile is reported. The 1:2 coordination stoichiometry of the complexes were confirmed by elemental analysis, mass spectrometry and NMR spectroscopy, and they were found to be consistent with a four-coordinate geometry.

Graphical abstractA novel class of mercury(II) complexes [L2Hg] with sugar-derived bidentade isothioureido ligands has been synthesized by treatment of N-acylated thioureas with yellow mercury(II) oxide, and characterized by CHN analysis, IR, mass spectrometry and NMR spectroscopy.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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