| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1338909 | Polyhedron | 2009 | 9 Pages |
Abstract
In Ru(II) complexes of formula [Ru(L)2(PPh3)2] (LHÂ =Â 4-(aryl)thiosemicarbazones of thiophen-2-carbaldehyde) ruthenium is six coordinate with a distorted octahedral cis-P2, cis-N2, trans-S2 donor environment, and each of the two thiosemicarbazones are coordinated forming a four membered chelate ring. EPR and DFT calculations suggest that the assignment of metal atom oxidation states in these compounds is not unambiguous.
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Authors
Sumita Naskar, Subhendu Naskar, Mike G.B. Drew, Serge I. Gorelsky, Benedikt Lassalle-Kaiser, Ally Aukauloo, Dipankar Mishra, Shyamal Kumar Chattopadhyay,