| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1338976 | Polyhedron | 2010 | 5 Pages |
A series of neutral palladium(IV) hydride complexes supported by β-ketoimine ligands was synthesized. Reaction of dichlorobis(acetonitrile)palladium(II) with β-ketoamines (1–4) in dichloromethane at room temperature generated dark red solids of [PdCl2(β-ketoimine)(H)] (6–9) in which the central carbon of the ketoimine ligand is σ-bound to the palladium. All the new complexes have been characterized by NMR and IR spectroscopy. The structure of complex(9) has been solved by X-ray crystallography.
Graphical abstractNew neutral hydride complexes of palladium(IV) supported by β-ketoimine ligands have been synthesized and characterized. The X-ray structure determination of the complex (9) reveals that it adopts a distorted square planar arrangement. The central carbon atom of the β-ketoimine ligand is σ-bound to a PdCl2 fragment.Figure optionsDownload full-size imageDownload as PowerPoint slide
