Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen with host (nanopores of zeolite-Y)/guest (Ni(II) complexes of 14- and 16-membered tetraaza dioxo diphenyl macrocyclic ligands) nanocomposite materials

Ni(II) complexes of [14]aneN4: 1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane; [16]aneN4: 1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane; Bzo2[14]aneN4: dibenzo-1,5,8,12-tetraaza-2,9-dioxo-4,11-diphenylcyclotetradecane and Bzo2[16]aneN4: dibenzo-1,5,9,13-tetraaza-2,10-dioxo-4,12-diphenylcyclohexadecane have been encapsulated in the nanopores of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of [bis(diamine)nickel(II)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene); [Ni(N–N)2]2+–NaY; in the nanopores of the zeolite-Y, and (ii) in situ condensation of the nickel(II) precursor complex with ethylcinnamate. The new host–guest nanocomposite materials (HGNM) were characterized by several techniques: chemical analysis and spectroscopic methods (FT-IR, UV/Vis, XRD and DRS) and the BET technique. These complexes were used for oxidation of cyclohexene with molecular oxygen.

Graphical abstractNi(II) complexes of 14- and 16-membered tetraaza macrocycles have been encapsulated in the nanopores of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of [bis(diamine)nickel(II)]; [Ni(N-N)2]2+-NaY; in the nanopores of the zeolite-Y, and (ii) in situ condensation of the nickel(II) precursor complex with ethylcinnamate. These complexes were used for oxidation of cyclohexene with molecular oxygen.Figure optionsDownload full-size imageDownload as PowerPoint slide