Article ID Journal Published Year Pages File Type
1339229 Polyhedron 2008 4 Pages PDF
Abstract
Two six coordinate tantalum(V) oxazoline complexes, [Ta(OX)(NMe2)4] (1) and [Ta(OX)2(NMe2)3] (2), formed by the reaction of [Ta(NMe2)5] with the chelating di-nitrogen ligand 4,4-dimethyl-2-pyrrole-2-oxazoline in 1:1, 1:2 and/or 1:3 molar ratios have been investigated. The structural study of 1 and 2 by X-ray crystallography shows that they both adopt geometries best described as distorted octahedral.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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