Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1339353 | Polyhedron | 2006 | 4 Pages |
Abstract
The reaction of V0(CO)6 and in situ electrochemically generated Ni[S2C2(CN)2]2, Ni(mnt)2, forms V{Ni[S2C2(CN)2]2}2 [νCN at 2202 cm−1], which exhibits antiferromagnetic coupling (θ ∼ −400 K) and does not magnetically order above 5 K. The reaction of [MII(NCMe)6]2+ (M = V, Cr, Mn, Fe, Co, Ni) and S = 1/2 [M(mnt)2]2− (M′ = Co, Cu) forms MII′[M(mnt)2] that exhibit antiferromagnetic coupling and do not magnetically order above 5 K.
Graphical abstractV{Ni[S2C2(CN)2]2}2 an analog the room temperature V[TCNE]x magnet exhibits antiferromagnetic coupling (θ ∼ −400 K) and does not magnetically order.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Laura Turnbow, Joel S. Miller,