| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1339530 | Polyhedron | 2010 | 5 Pages |
A series of nickel(II) complexes having the (Me-Tp)2PMA ligand ((Me-Tp)2PMA = bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine) with nitrates (1), chlorides (2), and perchlorates (3) as anions were synthesized and isolated. All these complexes were successfully characterized by physicochemical methods including X-ray crystallographic analysis. In complex 1, the ligand binds in a bidentate N2 fashion, whereas in the cases of 2 and 3 the ligand binds in the tridentate N2S form. The coordination geometry around the nickel(II) atoms in these complexes is distorted octahedral.
Graphical abstractA series of nickel(II) complexes containing a (Me-Tp)2PMA ligand ((Me-Tp)2PMA = bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine) with nitrates (1), chlorides (2), and perchlorates (3) as anions were successfully synthesized and characterized by physicochemical methods including X-ray crystallographic analysis. In complex 1, the ligand binds in a bidentate N2 fashion, whereas in the cases of 2 and 3 the ligand binds in the tridentate N2S form.Figure optionsDownload full-size imageDownload as PowerPoint slide
