Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1339539 | Polyhedron | 2010 | 7 Pages |
The metallation of two homologous, unsymmetrical BAI (1,3-bis(aryliminio)isoindoline) ligands with palladium acetate leads to square–planar cyclometallated PdII complexes, comprising a C–H bond activated dianionic and tetradentate BAI ligand. In the solid state these isostructural monomeric complexes form a structural motif containing large voids, despite the absence of other than dispersive intermolecular interactions.
Graphical abstractA simple and efficient one-pot synthesis of unsymmetrical BAI ligands is reported. The C–H bond activated palladium(II) complexes of two tailor-made unsymmetrical BAI ligands form, in the solid state, a structure containing large voids, despite the absence of other than dispersive intermolecular interactions.Figure optionsDownload full-size imageDownload as PowerPoint slide