| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1339737 | Polyhedron | 2007 | 5 Pages |
Abstract
The synthesis and structure of (E)-[Me(Me3Si)3SiSiO]2M (2), where M is titanium and zirconium, are reported. Both compounds react with TiCl4 and ZrCl4, respectively, to yield the complexes (E)-[Me(Me3Si)3SiSiO]2MCl2 (3). Upon treatment with 3Â equiv. of TiCl4, the titanium compound 2 readily undergoes a ring opening reaction to produce the dinuclear complex a (E)-[Me(Me3Si)3SiSiO]2Ti2Cl6 (4).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
C. Krempner, H. Reinke, K. Weichert,