Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1339847 | Polyhedron | 2007 | 5 Pages |
Abstract
The title complex is made up of centrosymmetric S-shaped pentanuclear [{Cu(cyclam)}3{Fe(CN)6}2] units, held together by two weak and complementary Fe-CNâ¯Cu bonds to form a rope-ladder chain. Interestingly enough, the ferromagnetic interaction between Cu(II) and Fe(III) ions through the long Cu-N axial bonds is not so weak as is usually assumed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Antonio RodrÃguez-Diéguez, Enrique Colacio,