Article ID Journal Published Year Pages File Type
1339847 Polyhedron 2007 5 Pages PDF
Abstract
The title complex is made up of centrosymmetric S-shaped pentanuclear [{Cu(cyclam)}3{Fe(CN)6}2] units, held together by two weak and complementary Fe-CN⋯Cu bonds to form a rope-ladder chain. Interestingly enough, the ferromagnetic interaction between Cu(II) and Fe(III) ions through the long Cu-N axial bonds is not so weak as is usually assumed.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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