| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1339896 | Polyhedron | 2009 | 4 Pages |
Abstract
The employment of 1,1,1-tris(hydroxymethyl)ethane ligand in higher oxidation state Mn cluster chemistry has yielded a new hexanuclear, mixed-valence (II,III,IV) compound with a rare [Mn6(μ6-O)]18+ octahedral core. The Mn6 molecule is completely ferromagnetically coupled and possesses an S = 11 ground state, the maximum for a MnII, 2MnIII, 3MnIV species.
Graphical abstractA new MnII/III/IV6 cluster with an octahedral topology has been obtained from the use of 1,1,1-tris(hydroxymethyl)ethane (thmeH3) in higher oxidation state Mn cluster chemistry. The complex is entirely ferromagnetically coupled, possessing the maximum possible S = 11 ground state.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Theocharis C. Stamatatos, Konstantina V. Pringouri, Khalil A. Abboud, George Christou,