| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1339901 | Polyhedron | 2009 | 4 Pages |
Employing the mononuclear complex [Ni{(py)C(Me)NO}2{(py)C(Me)NOH}] (1) as ‘ligand’ [(py)C(Me)NOH = methyl 2-pyridyl ketone oxime], the use of the ‘metal complexes as ligands’ approach has led to the synthesis of the mixed NiII/LnIII complexes [NiTb{(py)C(Me)NO}2(NO3)3{(py)C(Me)NOH}] (2), [Ni2Ln2{(py)C(Me)NO}6(NO3)4] (Ln = Dy, 3; Ln = Tb, 4) and [Ni2Tb{(py)C(Me)NO}6](NO3) (5). The structures of 2, 3, and 5, and the magnetic properties of 2 and 5 are briefly discussed.
Graphical abstractEmploying methyl 2-pyridyl ketone oxime, the ‘metal complexes as ligand’ strategy and various ‘one-pot’ approaches, NiTb, Ni2Tb2, Ni2Ln2, and Ni2Tb complexes with interesting structural and magnetic features were prepared.Figure optionsDownload full-size imageDownload as PowerPoint slide
