Article ID Journal Published Year Pages File Type
1339923 Polyhedron 2009 4 Pages PDF
Abstract

Three highly π-extended tetraaryl-1,3-phenylenediamines for charged high-spin molecular systems were successfully synthesized using Suzuki coupling. Their electrochemical and spectroscopic properties were also examined. They showed blue fluorescence. The dications derived from highly π-extended tetraaryl-1,3-phenylenediamines were generated and characterized by electron transfer stopped-flow method.

Graphical abstractA series of highly π-extended tetraaryl-m-phenylenediamines were designed and synthesized as a precursor of positively charged high-spin systems. The electrochemical and spectroscopic properties were examined.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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