Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1339923 | Polyhedron | 2009 | 4 Pages |
Abstract
Three highly π-extended tetraaryl-1,3-phenylenediamines for charged high-spin molecular systems were successfully synthesized using Suzuki coupling. Their electrochemical and spectroscopic properties were also examined. They showed blue fluorescence. The dications derived from highly π-extended tetraaryl-1,3-phenylenediamines were generated and characterized by electron transfer stopped-flow method.
Graphical abstractA series of highly π-extended tetraaryl-m-phenylenediamines were designed and synthesized as a precursor of positively charged high-spin systems. The electrochemical and spectroscopic properties were examined.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Masafumi Yano, Yorichika Okino, Yuji Ichihara, Masakazu Tatsumi, Munetaka Oyama, Kazunobu Sato, Takeji Takui,