Article ID Journal Published Year Pages File Type
1339947 Polyhedron 2009 5 Pages PDF
Abstract

A triamine, 2,2′,4,4′-tetrabromo-3″,4″-dimethyl-5,5′-bis(di(4-methylphenyl)amino)triphenylamine, was designed and synthesized as a model precursor for purely organic cationic high-spin systems. Cyclic voltammetry measurements revealed that the triamine gives stable mono-, di-, and tricationic states at ambient temperature. Novel electron transfer stopped-flow (ETSF) methods were invoked for characterizing the absorption spectra of the corresponding mono- and oligo-cationic states. The triamine-based trication was generated by chemical oxidation at room temperature, and the triamine was quantitatively recovered upon reduction. The electronic ground state of the trication is discussed.

Graphical abstractA polyalkylated oligoaryl triamine was designed and synthesized as a precursor of positively charged high-spin systems. The highly oxidized tricationic state is very stable at ambient temperature for 15 min. The electrochemical and spectroscopic properties were examined.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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