Article ID Journal Published Year Pages File Type
1340002 Polyhedron 2006 5 Pages PDF
Abstract
2,2′-Bipyridine ligand in Rh(I) complexes undergoes H3,3′-D3,3′ exchange in basic solution CD3ONa/CD3OD. The hydride resonances in the range −14 to −28 ppm are observed although the only hydrogen source is bpy ligand. This strongly suggests that oxidative addition of C3-H to rhodium takes place in the exchange process.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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