| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1340039 | Polyhedron | 2007 | 4 Pages |
Abstract
The combination of MnBr2 · 4H2O with tripodal alcohols results in the formation of new octa- and dodecametallic [Mn4IIIMn4II] and [Mn6IIIMn6II] clusters. Their structures describe ‘one-dimensional’ rod-like arrays of six and ten edge-sharing triangles, respectively. Both complexes display S ≈ 0 spin ground states.
Graphical abstractThe combination of MnBr2 · 4H2O with tripodal alcohols results in the formation of new octa- and dodecametallic [Mn4IIIMn4II] and [Mn6IIIMn6II] clusters. Their structures describe ‘one-dimensional’ rod-like arrays of six and ten edge-sharing triangles, respectively. Both complexes display S ≈ 0 spin ground states.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Maria Manoli, Constantinos J. Milios, Abhudaya Mishra, George Christou, Euan K. Brechin,