| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1340051 | Polyhedron | 2012 | 5 Pages |
A polyalkylated triamine, 2,2′,4,4′-tetrabromo-4″-methyl-5,5′-bis(di(3,4-di-methylphenyl)amino)triphenylamine, was designed and successfully synthesized as a model precursor for purely organic cationic high-spin systems. Cyclic voltammetry measurement revealed that the triamine gives stable mono- and dicationic states and fairly unstable tricationic state. Novel electron transfer stopped-flow (ETSF) methods were invoked for characterizing the absorption spectra of the corresponding mono- and oligo-cationic states. The triplet state of the dication was confirmed by ESR spectroscopy.
Graphical abstractA polyalkylated oligoaryl triamine was designed and synthesized as a precursor of positively charged high-spin systems. The electrochemical and spectroscopic properties were examined.Figure optionsDownload full-size imageDownload as PowerPoint slide
