Article ID Journal Published Year Pages File Type
1340079 Polyhedron 2007 4 Pages PDF
Abstract
The distortion imposed on two [Mn3(μ3-O)]7+ members of the well known and well studied class of triangular, oxide-centered [Mn3O(O2CR)6(py)3]+ complexes by methyl or phenyl 2-pyridyl ketone oxime (L'H) switches the exchange interactions to ferromagnetic and makes the [Mn3O(O2CR)3L3′]+ products the first examples of triangular single-molecule magnets.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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