Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1340220 | Polyhedron | 2007 | 7 Pages |
Abstract
Strategies for the construction of TMS-protected first generation star and dendritic polyynes, which are subsequently metallated to give multiple Co2C2(CO)6 clusters, are reported. In the absence of crystallographic data, well-resolved 13C NMR spectroscopy is a powerful technique for confirming the presence of core, inner and peripheral cluster domains.
Graphical abstractStrategies for the construction of TMS-protected first generation star and dendritic polyynes, which can subsequently fully functionalized with Co2(CO)6-cluster units, are reported. 13C NMR spectroscopy is shown to be the most valuable tool in the characterization of the cobalt cluster-decorated products.Figure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Edwin C. Constable, Deborah Gusmeroli, Catherine E. Housecroft, Markus Neuburger, Silvia Schaffner,