Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1340320 | Polyhedron | 2007 | 11 Pages |
Abstract
Discrete polymeric chains of trans catena-poly[(N,N-diethylglycinato-κO,κN)copper(II)-μ-[N,N-diethylglycinato-κO1,κN:O2]] were produced by axial coordinative bonding between copper(II) and carbonyl oxygen atom from adjacent asymmetric unit in the crystal structure. Steric aliphatic-aliphatic interactions between flexible ethyl chains are successfully reproduced, and conformational change of the complex upon crystallization is predicted using molecular mechanics force field.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jasmina SaboloviÄ, Branko Kaitner,