Article ID Journal Published Year Pages File Type
1340320 Polyhedron 2007 11 Pages PDF
Abstract
Discrete polymeric chains of trans catena-poly[(N,N-diethylglycinato-κO,κN)copper(II)-μ-[N,N-diethylglycinato-κO1,κN:O2]] were produced by axial coordinative bonding between copper(II) and carbonyl oxygen atom from adjacent asymmetric unit in the crystal structure. Steric aliphatic-aliphatic interactions between flexible ethyl chains are successfully reproduced, and conformational change of the complex upon crystallization is predicted using molecular mechanics force field.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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