Article ID Journal Published Year Pages File Type
1340409 Polyhedron 2006 4 Pages PDF
Abstract
The reaction of TCNE and V(CO)6 and several solvents (S) form an immediate black precipitate of V(TCNE)x · yS (S = solvent; x ∼ 2; y ∼ 0.5), which have a magnetic ordering onset temperature in the range of 385-390 K. When S = PhCF3 in addition to the onset temperature being enhanced it exhibits greater thermal stability.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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