Article ID Journal Published Year Pages File Type
1340453 Polyhedron 2006 6 Pages PDF
Abstract
Cis-[M(CO)4(α/β-NaiR′)] (M = Cr(0), Mo(0) and α/β-NaiR′ = 1-alkyl-2-(naphthyl-α/β-azo)-imidazoles) are described in this work. Fluorescence shows a π-π∗ emission. Cyclic voltammetry gives two metal centred oxidations, M+/M0 and M2+/M+, and two ligand centred reductions, azo/azo− and azo−/azo=.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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