Article ID Journal Published Year Pages File Type
1340759 Polyhedron 2007 7 Pages PDF
Abstract
Photolysis of the nitroxyl complex Os(N(O)H)(CO)Cl2(PPh3)2 shows multiple products that are interpreted in terms of two competing, primary photoreactions, the reversible dissociation of HNO (which dimerizes to N2O) and the dissociation of CO. The relative yields of products varied depending on whether or not excess CO was present.
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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Thermal and photochemical reactivity of Os(HNO)(CO)Cl2(PPh3)2: Evidence for photochemical HNO generation
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