| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1340787 | Polyhedron | 2005 | 7 Pages |
Abstract
The synthesis and structures of nickel (II) complexes of chiral cyclams originating from l-proline are presented. Upon addition of nickel acteate, oxocyclams having amide groups underwent deprotonation forming distorted square-planar complexes. In the case of the all-amine analogue a six-coordinate octahedral complex is formed.
Graphical abstractThe nickel (II) complexes of the chiral cyclam and its mono- and dioxo derivatives show different complexation modes as proved by the X-ray analysis.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Agnieszka Szumna, Michał Achmatowicz, Tomasz Zieliński, Janusz Jurczak,