| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1341053 | Polyhedron | 2005 | 4 Pages |
Abstract
A ligand, 4-(bis(2-picolyl)aminomethyl)-4′,4″-dimethyltriphenylamine ((2-py)2TPA) and its copper complex were designed and prepared in order to examine intramolecular interactions of organic cation radical–metal ion. CV measurements of the copper complex showed reversible CuI/CuII and TPA/TPA+· redox couples. The spin–spin interaction in [Cu((2-py)2TPA)Cl]2+ generated upon one electron oxidation of the copper complex was examined by ESR measurements.
Graphical abstractA novel ligand with a redox active triarylsamine unit and its copper complex were designed and synthesized. Electrochemical and spectroscopic properties of the complex were examined.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Masafumi Yano, Kazutoshi Inoue, Takeshi Motoyama, Yasuhiro Azuma, Masakazu Tatsumi, Osamu Yamauchi, Munetaka Oyama, Kazunobu Sato, Takeji Takui,