| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1341055 | Polyhedron | 2005 | 5 Pages |
Two types of iodinated tetraaryl-1,3-phenylenediamine were designed and synthesized as useful building blocks for synthons in organic syntheses. Various highly π-extended tetraaryl-1,3-phenylenediamines for charged high-spin molecular systems were successfully synthesized from the precursors using Sonogashira coupling. Their electrochemical and spectroscopic properties were also examined. The dications derived from highly π-extended tetraaryl-1,3-phenylenediamines were generated and characterized by electron transfer stopped-flow method. Some of the monocation radicals were short-lived.
Graphical abstractVarious highly π-extended tetraaryl-1,3-phenylenediamines were synthesized. Their electrochemical and spectroscopic properties were also examined.Figure optionsDownload full-size imageDownload as PowerPoint slide
