Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1341106 | Polyhedron | 2005 | 7 Pages |
Abstract
We determined hyperfine coupling constants of the imidazole ligand in a ferromagnetic coordination polymer, di-μ-thiocyanatobis(imidazole)nickel(II), using 1H-, 2H-, and 13C-MAS-NMR. An interchain superexchange pathway through N-S hydrogen bond was proposed on the basis of the delocalization of the unpaired electron in dx2-y2 orbital of Ni(II) ion over the imidazole ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Goro Maruta, Sadamu Takeda,