Article ID Journal Published Year Pages File Type
1401740 Journal of Molecular Structure 2015 7 Pages PDF
Abstract
Synthesis of thioether containing NSNO donor azo ligand (HL) showing hydrazoketo and azoenol tautomerism has been carried out. The hydrazoketo form of HL is predominating over azoenol form. In copper(II) complex the ligand is present as azoenol form. The electronic spectra and electronic structure of the complex has been extensively studied. The structures of the ligand and copper(II) complex have been established from single crystal X-ray studies. The 1-D supramolecular structure of the complex is formed by π-π interactions.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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