Article ID Journal Published Year Pages File Type
1402868 Journal of Molecular Structure 2013 7 Pages PDF
Abstract

Two tryptophan-based pyridine dicarboxamide ligands have been synthesised and characterised. 1H NMR studies indicated that these ligands are capable of coordinating to bromide anions through amide/indole NH and CH groups. Based on 1H NMR studies, we found that organic bromides selectively bind to with one of the ligands, as evidenced by complexation induced chemical shifts for the indole and amide NH resonances.

Graphical abstractTwo tryptophan-based pyridine dicarboxamide ligands have been synthesised and characterized. 1H NMR studies indicated that these ligands are capable of coordinating to bromide anions through amide/indole NH and CH groups. Based on 1H NMR studies, we found that organic bromides selectively bind to with one of the ligands, as evidenced by complexation induced chemical shifts for the indole and amide NH resonances.Figure optionsDownload full-size imageDownload as PowerPoint slide

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Physical Sciences and Engineering Chemistry Organic Chemistry
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